Brine Purification

Brine Purification

In chlor-alkali production plants based on membrane electrolysis, the feed sodium chloride (or potassium chloride) brine must be treated to a very high quality i.e. no suspended solids and very low residual hardness is admitted (few ppbs of calcium, magnesium, strontium).
Unidro has a wide record of experiences in designing and supplying tailor made units for each of the main sections of the brine treatment chain: clarification of the saturated brine, filtration of the clarified brine, super-purification of the filtered brine by means of chelate resin towers.

Clarification

For the clarification of the saturated brine Unidro can propose either a conventional circular-shaped clarifier provided with sludge scraper, or a rectangular settling tank equipped with internals lamella.
Large equipment are normally delivered prefabricated and lined at shop, ready for assembly by bolting only at site.

Rectangular settlers are selected when a very compact system is desired and are delivered as fully pre-fabricated tanks.

Filtration

Filtration can be accomplished by two steps in series: the first on anthracite filters, to remove the large majority of residual suspended solids; the second on precoat candle filters, to provide a very fine filtration and remove particles larger than 1 micron.
Unidro can provide high-performance anthracite filters, which incorporate a special backwash concept.
Unidro precoat filters based on different type of precoatable candles.

Super-purification (Chelate Resin Units)

The super-purification of brine is achieved by treating the filtered brine in a chelate resin towers unit.
This unit typically includes three resin columns connected in series.
Regeneration through a complex sequence of steps is fully automatic and operated.

Chelate Resin

Iminodiacetic acid chelating resin MCR10

Amino phosphonic chelation resin MCR50